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Aromatic isocyanates are of ever-increasing importance in recent years. This applies especially to aliphatic diisocyanates, which are the compounds mainly used for making polyurethanes. The aliphatic diisocyanates, used for example for polyurethanes, are obtained by reacting aromatic diisocyanates with aliphatic alcohols. Apart from employing them directly as raw materials for polyurethane (PU) production, the aromatic isocyanates are also valuable intermediate products for the production of other compounds. Thus, for example, aromatic isocyanates can be converted into diphenyl methane diisocyanate, which is employed as a crosslinking agent in the manufacture of flexible polyurethane foams.
At present, two processes are mainly used for producing aromatic isocyanates. Both of these employ phosgenation as a primary reaction. In the first known process, 1,2-dichloroethane is reacted with phosgene to give 4-chloro-2,2-bis(chloromethyl)propane. This reaction product is separated by distillation and subsequently treated with methyl alcohol to give the desired 4-methyldiphenylmethane diisocyanate